Title
Isolation and characterisation of the pyridazine (pydz) bridged halogenotrimethylplatinum(IV) complexes [(PtXMe₃)₂(μ-pydz)] (X = Cl, Br or I). X-Ray structure of [(PtIMe₃)₂(μ-pydz)]
Abstract
The bridged dinuclear platinum(IV) complexes [(PtXMe₃)₂( μ-pydz)] (X = Cl, Br, I) were isolated as minor products from the reaction between pyridazine (pydz) and the halogenotrimethylplatinum(IV) tetramers. The X-ray crystal structure of the iodo complex reveals both a double halide bridge and a pyridazine bridged structure with a Pt Pt non-bonded distance of 3.5937(5) Å. The platinum atoms show only a slight deviation from an idealized octahedral geometry, but the structure is folded in the equatorial plane by 51.5° to accommodate the iodines between the two platinum moieties.
Disciplines
Chemistry | Inorganic Chemistry | Organic Chemistry | Physical Chemistry
Recommended Citation
Abel, E. W., Heard, P. J., Orrell, K. G., Hursthouse, M. B., &. Malik, K. M. A. (1994) “Isolation and characterisation of the pyridazine (pydz) bridged halogenotrimethylplatinum(IV) complexes [(PtXMe₃)₂(μ-pydz)] (X = Cl, Br or I). X-Ray structure of [(PtIMe₃)₂(μ-pydz)]”. Polyhedron, 13(17), 2501-2505
Digital Commons Citation
Abel, Edward W.; Heard, Peter J.; Orrell, Keith G.; Hursthouse, Michael B.; and Malik, Abdul K., "Isolation and characterisation of the pyridazine (pydz) bridged halogenotrimethylplatinum(IV) complexes [(PtXMe₃)₂(μ-pydz)] (X = Cl, Br or I). X-Ray structure of [(PtIMe₃)₂(μ-pydz)]" (1994). Chemistry. Paper 7.
http://epubs.glyndwr.ac.uk/chem/7
Comments
Only metadata available from this site. Copyright © 1994 Published by Elsevier Science Ltd. All rights reserved. This article was originally published in the Polyhedron Journal by Elsevier in 1994. The full article can be found at http://www.sciencedirect.com