Title
Formation of dimethylamine complexes of trimethylplatinum(IV) from reactions with N,N,N’,N’-tetramethyldiaminomethane
Abstract
Attempts to prepare complexes of trimethylplatinum(IV) with N,N,N′N′-tetramethyldiaminomethane (TMDM) as either a chelating or bridging ligand gave only the complexes of dimethylamine [PtMe₃X(HNMe₂))]₂(X = Cl, Br and I ; 1–3 and [PtMe₃((2,2′-bipyridyil) (HNMe₂))]⁺[[BF₄]]⁺ (4)). ¹HH NMR evidence showed that only one of the two possible isomers was formed for 1–3.
Disciplines
Chemistry | Inorganic Chemistry | Organic Chemistry | Physical Chemistry
Recommended Citation
Abel, E. W., Goldsworthy, D. H., Heard, P. J., & Kite, K. (1995) ‘Formation of dimethylamine complexes of trimethylplatinum(IV) from reactions with N,N,N’,N’-tetramethyldiaminomethane’. Polyhedron, 14(4), 515-519.
Digital Commons Citation
Abel, Edward W.; Goldsworthy, Duncan H.; Heard, Peter J.; and Kite, Kenneth, "Formation of dimethylamine complexes of trimethylplatinum(IV) from reactions with N,N,N’,N’-tetramethyldiaminomethane" (1995). Chemistry. Paper 5.
http://epubs.glyndwr.ac.uk/chem/5
Comments
Copyright © 1995 Published by Elsevier Ltd. Only metadata available from this website. This article was originally published in the Polyhedron Journal in 2003 by Elsevier, the full article can be found at http://www.sciencedirect.com